S2 := HttpEncode(UTF8Encode(S1));

S1 := UTF8Decode(HttpDecode(S2));

//URLEncode
function URLDecode(const S: string): string;
var
  Idx: Integer;   // loops thru chars in string
  Hex: string;    // string of hex characters
  Code: Integer;  // hex character code (-1 on error)
begin
  // Intialise result and string index
  Result := '';
  Idx := 1;
  // Loop thru string decoding each character
  while Idx <= Length(S) do
  begin
    case S[Idx] of
      '%':
      begin
        // % should be followed by two hex digits - exception otherwise
        if Idx <= Length(S) - 2 then
        begin
          // there are sufficient digits - try to decode hex digits
          Hex := S[Idx+1] + S[Idx+2];
          Code := SysUtils.StrToIntDef('$' + Hex, -1);
          Inc(Idx, 2);
        end
        else
          // insufficient digits - error
          Code := -1;
        // check for error and raise exception if found
        if Code = -1 then
          raise SysUtils.EConvertError.Create(
            'Invalid hex digit in URL'
          );
        // decoded OK - add character to result
        Result := Result + Chr(Code);
      end;
      '+':
        // + is decoded as a space
        Result := Result + ' '
      else
        // All other characters pass thru unchanged
        Result := Result + S[Idx];
    end;
    Inc(Idx);
  end;
end;

//URLDecode 
function URLEncode(const S: string; const InQueryString: Boolean): string;
var
  Idx: Integer; // loops thru characters in string
begin
  Result := '';
  for Idx := 1 to Length(S) do
  begin
    case S[Idx] of
      'A'..'Z', 'a'..'z', '0'..'9', '-', '_', '.':
        Result := Result + S[Idx];
      ' ':
        if InQueryString then
          Result := Result + '+'
        else
          Result := Result + '%20';
      else
        Result := Result + '%' + SysUtils.IntToHex(Ord(S[Idx]), 2);
    end;
  end;
end;

uses 
  Httpapp; 

begin
  sStr:=HttpEncode(UTF8EnCode('滔Roy'));
  //或：
  //sStr:=HttpEncode(AnsiToUtf8('滔Roy'));
end;

uses
  IdURI;

begin
  sStr := TIdURI.URLEncode(str);
//
  sStr := TIdURI.URLDecode(str);
end;