<?php 
$array[] = array("age"=>20,"name"=>"li");
$array[] = array("age"=>21,"name"=>"ai");
$array[] = array("age"=>20,"name"=>"ci");
$array[] = array("age"=>22,"name"=>"di");
 
foreach ($array as $key=>$value){
 $age[$key] = $value['age'];
 $name[$key] = $value['name'];
}
 
array_multisort($age,SORT_NUMERIC,SORT_DESC,$name,SORT_STRING,SORT_ASC,$array);
print_r($array);
?>

Array (
[0] => Array ( [age] => 22 [name] => di )
[1] => Array ( [age] => 21 [name] => ai )
[2] => Array ( [age] => 20 [name] => ci )
[3] => Array ( [age] => 20 [name] => li )
)