Python rdm.reorder_rdm函数代码示例

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本文整理汇总了Python中pyscf.fci.rdm.reorder_rdm函数的典型用法代码示例。如果您正苦于以下问题：Python reorder_rdm函数的具体用法？Python reorder_rdm怎么用？Python reorder_rdm使用的例子？那么恭喜您, 这里精选的函数代码示例或许可以为您提供帮助。

在下文中一共展示了reorder_rdm函数的16个代码示例，这些例子默认根据受欢迎程度排序。您可以为喜欢或者感觉有用的代码点赞，您的评价将有助于我们的系统推荐出更棒的Python代码示例。

示例1: spin_square

def spin_square(fcivec, norb, nelec, mo_coeff=None, ovlp=1):
    r'''General spin square operator.

    ... math::

        <CI|S_+*S_-|CI> &= n_\alpha + \delta_{ik}\delta_{jl}Gamma_{i\alpha k\beta ,j\beta l\alpha } \\
        <CI|S_-*S_+|CI> &= n_\beta + \delta_{ik}\delta_{jl}Gamma_{i\beta k\alpha ,j\alpha l\beta } \\
        <CI|S_z*S_z|CI> &= \delta_{ik}\delta_{jl}(Gamma_{i\alpha k\alpha ,j\alpha l\alpha }
                         - Gamma_{i\alpha k\alpha ,j\beta l\beta }
                         - Gamma_{i\beta k\beta ,j\alpha l\alpha}
                         + Gamma_{i\beta k\beta ,j\beta l\beta})
                         + (n_\alpha+n_\beta)/4

    Given the overlap betwen non-degenerate alpha and beta orbitals, this
    function can compute the expectation value spin square operator for
    UHF-FCI wavefunction
    '''
    from pyscf.fci import direct_spin1
    neleca, nelecb = _unpack(nelec)

    if isinstance(mo_coeff, numpy.ndarray) and mo_coeff.ndim == 2:
        mo_coeff = (mo_coeff, mo_coeff)
    elif mo_coeff is None:
        mo_coeff = (numpy.eye(norb),) * 2

# projected overlap matrix elements for partial trace
    if isinstance(ovlp, numpy.ndarray):
        ovlpaa = reduce(numpy.dot, (mo_coeff[0].T, ovlp, mo_coeff[0]))
        ovlpbb = reduce(numpy.dot, (mo_coeff[1].T, ovlp, mo_coeff[1]))
        ovlpab = reduce(numpy.dot, (mo_coeff[0].T, ovlp, mo_coeff[1]))
        ovlpba = reduce(numpy.dot, (mo_coeff[1].T, ovlp, mo_coeff[0]))
    else:
        ovlpaa = numpy.dot(mo_coeff[0].T, mo_coeff[0])
        ovlpbb = numpy.dot(mo_coeff[1].T, mo_coeff[1])
        ovlpab = numpy.dot(mo_coeff[0].T, mo_coeff[1])
        ovlpba = numpy.dot(mo_coeff[1].T, mo_coeff[0])

    # if ovlp=1, ssz = (neleca-nelecb)**2 * .25
    (dm1a, dm1b), (dm2aa, dm2ab, dm2bb) = \
            direct_spin1.make_rdm12s(fcivec, norb, nelec)
    ssz =(_bi_trace(dm2aa, ovlpaa, ovlpaa)
        - _bi_trace(dm2ab, ovlpaa, ovlpbb)
        + _bi_trace(dm2bb, ovlpbb, ovlpbb)
        - _bi_trace(dm2ab, ovlpaa, ovlpbb)) * .25 \
        +(_trace(dm1a, ovlpaa)
        + _trace(dm1b, ovlpbb)) *.25

    dm2baab = _make_rdm2_baab(fcivec, norb, nelec)
    dm2abba = _make_rdm2_abba(fcivec, norb, nelec)
    dm2baab = rdm.reorder_rdm(dm1b, dm2baab, inplace=True)[1]
    dm2abba = rdm.reorder_rdm(dm1a, dm2abba, inplace=True)[1]
    ssxy =(_bi_trace(dm2abba, ovlpab, ovlpba)
         + _bi_trace(dm2baab, ovlpba, ovlpab) \
         + _trace(dm1a, ovlpaa)
         + _trace(dm1b, ovlpbb)) * .5
    ss = ssxy + ssz

    s = numpy.sqrt(ss+.25) - .5
    multip = s*2+1
    return ss, multip

开发者ID:pengdl，项目名称:pyscf，代码行数:60，代码来源:spin_op.py

示例2: make_rdm12s

def make_rdm12s(fcivec, norb, nelec, link_index=None, reorder=True):
    r'''Spin separated 1- and 2-particle density matrices.
    The return values include two lists, a list of 1-particle density matrices
    and a list of 2-particle density matrices.  The density matrices are:
    (alpha,alpha), (beta,beta) for 1-particle density matrices;
    (alpha,alpha,alpha,alpha), (alpha,alpha,beta,beta),
    (beta,beta,beta,beta) for 2-particle density matrices.

    1pdm[p,q] = :math:`\langle q^\dagger p\rangle`;
    2pdm[p,q,r,s] = :math:`\langle p^\dagger r^\dagger s q\rangle`.

    Energy should be computed as
    E = einsum('pq,qp', h1, 1pdm) + 1/2 * einsum('pqrs,pqrs', eri, 2pdm)
    where h1[p,q] = <p|h|q> and eri[p,q,r,s] = (pq|rs)
    '''
    dm1a, dm2aa = rdm.make_rdm12_spin1('FCIrdm12kern_a', fcivec, fcivec,
                                       norb, nelec, link_index, 1)
    dm1b, dm2bb = rdm.make_rdm12_spin1('FCIrdm12kern_b', fcivec, fcivec,
                                       norb, nelec, link_index, 1)
    _, dm2ab = rdm.make_rdm12_spin1('FCItdm12kern_ab', fcivec, fcivec,
                                    norb, nelec, link_index, 0)
    if reorder:
        dm1a, dm2aa = rdm.reorder_rdm(dm1a, dm2aa, inplace=True)
        dm1b, dm2bb = rdm.reorder_rdm(dm1b, dm2bb, inplace=True)
    return (dm1a, dm1b), (dm2aa, dm2ab, dm2bb)

开发者ID:chrinide，项目名称:pyscf，代码行数:25，代码来源:direct_spin1.py

示例3: trans_rdm12s

def trans_rdm12s(cibra, ciket, norb, nelec, link_index=None, reorder=True):
    r'''Spin separated 1- and 2-particle transition density matrices.
    The return values include two lists, a list of 1-particle transition
    density matrices and a list of 2-particle transition density matrices.
    The density matrices are:
    (alpha,alpha), (beta,beta) for 1-particle transition density matrices;
    (alpha,alpha,alpha,alpha), (alpha,alpha,beta,beta),
    (beta,beta,alpha,alpha), (beta,beta,beta,beta) for 2-particle transition
    density matrices.

    1pdm[p,q] = :math:`\langle q^\dagger p\rangle`;
    2pdm[p,q,r,s] = :math:`\langle p^\dagger r^\dagger s q\rangle`.
    '''
    dm1a, dm2aa = rdm.make_rdm12_spin1('FCItdm12kern_a', cibra, ciket,
                                       norb, nelec, link_index, 2)
    dm1b, dm2bb = rdm.make_rdm12_spin1('FCItdm12kern_b', cibra, ciket,
                                       norb, nelec, link_index, 2)
    _, dm2ab = rdm.make_rdm12_spin1('FCItdm12kern_ab', cibra, ciket,
                                    norb, nelec, link_index, 0)
    _, dm2ba = rdm.make_rdm12_spin1('FCItdm12kern_ab', ciket, cibra,
                                    norb, nelec, link_index, 0)
    dm2ba = dm2ba.transpose(3,2,1,0)
    if reorder:
        dm1a, dm2aa = rdm.reorder_rdm(dm1a, dm2aa, inplace=True)
        dm1b, dm2bb = rdm.reorder_rdm(dm1b, dm2bb, inplace=True)
    return (dm1a, dm1b), (dm2aa, dm2ab, dm2ba, dm2bb)

开发者ID:chrinide，项目名称:pyscf，代码行数:26，代码来源:direct_spin1.py

示例4: make_rdm12s

def make_rdm12s(fcivec, norb, nelec, link_index=None, reorder=True):
    dm1a, dm2aa = rdm.make_rdm12_spin1('FCIrdm12kern_a', fcivec, fcivec,
                                       norb, nelec, link_index, 1)
    dm1b, dm2bb = rdm.make_rdm12_spin1('FCIrdm12kern_b', fcivec, fcivec,
                                       norb, nelec, link_index, 1)
    _, dm2ab = rdm.make_rdm12_spin1('FCItdm12kern_ab', fcivec, fcivec,
                                    norb, nelec, link_index, 0)
    if reorder:
        dm1a, dm2aa = rdm.reorder_rdm(dm1a, dm2aa, inplace=True)
        dm1b, dm2bb = rdm.reorder_rdm(dm1b, dm2bb, inplace=True)
    return (dm1a, dm1b), (dm2aa, dm2ab, dm2bb)

开发者ID:diradical，项目名称:pyscf，代码行数:11，代码来源:direct_spin1.py

示例5: trans_rdm12s

def trans_rdm12s(cibra, ciket, norb, nelec, link_index=None, reorder=True):
    dm1a, dm2aa = rdm.make_rdm12_spin1('FCItdm12kern_a', cibra, ciket,
                                       norb, nelec, link_index, 2)
    dm1b, dm2bb = rdm.make_rdm12_spin1('FCItdm12kern_b', cibra, ciket,
                                       norb, nelec, link_index, 2)
    _, dm2ab = rdm.make_rdm12_spin1('FCItdm12kern_ab', cibra, ciket,
                                    norb, nelec, link_index, 0)
    _, dm2ba = rdm.make_rdm12_spin1('FCItdm12kern_ab', ciket, cibra,
                                    norb, nelec, link_index, 0)
    dm2ba = dm2ba.transpose(3,2,1,0)
    if reorder:
        dm1a, dm2aa = rdm.reorder_rdm(dm1a, dm2aa, inplace=True)
        dm1b, dm2bb = rdm.reorder_rdm(dm1b, dm2bb, inplace=True)
    return (dm1a, dm1b), (dm2aa, dm2ab, dm2ba, dm2bb)

开发者ID:diradical，项目名称:pyscf，代码行数:14，代码来源:direct_spin1.py

示例6: spin_square

def spin_square(ci, norb, nelec, mo_coeff=None, ovlp=1):
# <CI|S+*S-|CI> = neleca + \delta_{ik}\delta_{jl}Gamma_{iakb,jbla}
# <CI|S-*S+|CI> = nelecb + \delta_{ik}\delta_{jl}Gamma_{ibka,jalb}
# <CI|Sz*Sz|CI> = \delta_{ik}\delta_{jl}(Gamma_{iaka,jala} - Gamma_{iaka,jblb}
#                                       -Gamma_{ibkb,jala} + Gamma_{ibkb,jblb})
#               + (neleca+nelecb)/4
    if isinstance(nelec, (int, numpy.integer)):
        neleca = nelecb = nelec // 2
    else:
        neleca, nelecb = nelec

    if isinstance(mo_coeff, numpy.ndarray) and mo_coeff.ndim == 2:
        mo_coeff = (mo_coeff, mo_coeff)
    elif mo_coeff is None:
        mo_coeff = (numpy.eye(norb),) * 2

# projected overlap matrix elements for partial trace
    if isinstance(ovlp, numpy.ndarray):
        ovlpaa = reduce(numpy.dot, (mo_coeff[0].T, ovlp, mo_coeff[0]))
        ovlpbb = reduce(numpy.dot, (mo_coeff[1].T, ovlp, mo_coeff[1]))
        ovlpab = reduce(numpy.dot, (mo_coeff[0].T, ovlp, mo_coeff[1]))
        ovlpba = reduce(numpy.dot, (mo_coeff[1].T, ovlp, mo_coeff[0]))
    else:
        ovlpaa = numpy.dot(mo_coeff[0].T, mo_coeff[0])
        ovlpbb = numpy.dot(mo_coeff[1].T, mo_coeff[1])
        ovlpab = numpy.dot(mo_coeff[0].T, mo_coeff[1])
        ovlpba = numpy.dot(mo_coeff[1].T, mo_coeff[0])

    (dm1a, dm1b), (dm2aa, dm2ab, dm2bb) = \
            direct_spin1.make_rdm12s(ci, norb, nelec)
    ssz =(_bi_trace(dm2aa, ovlpaa, ovlpaa)
        - _bi_trace(dm2ab, ovlpaa, ovlpbb)
        + _bi_trace(dm2bb, ovlpbb, ovlpbb)
        - _bi_trace(dm2ab, ovlpaa, ovlpbb)) * .25 \
        +(_trace(dm1a, ovlpaa)
        + _trace(dm1b, ovlpbb)) *.25

    dm2baab = _make_rdm2_baab(ci, norb, nelec)
    dm2abba = _make_rdm2_abba(ci, norb, nelec)
    dm2baab = rdm.reorder_rdm(dm1b, dm2baab, inplace=True)[1]
    dm2abba = rdm.reorder_rdm(dm1a, dm2abba, inplace=True)[1]
    ssxy =(_bi_trace(dm2abba, ovlpab, ovlpba)
         + _bi_trace(dm2baab, ovlpba, ovlpab) \
         + _trace(dm1a, ovlpaa)
         + _trace(dm1b, ovlpbb)) * .5
    ss = ssxy + ssz

    s = numpy.sqrt(ss+.25) - .5
    multip = s*2+1
    return ss, multip

开发者ID:diradical，项目名称:pyscf，代码行数:50，代码来源:spin_op.py

示例7: make_rdm12e

def make_rdm12e(fcivec, nsite, nelec):
    '''1-electron and 2-electron density matrices
    dm_pq = <|p^+ q|>
    dm_{pqrs} = <|p^+ r^+ q s|>  (note 2pdm is ordered in chemist notation)
    '''
    neleca, nelecb = _unpack_nelec(nelec)
    link_indexa = cistring.gen_linkstr_index(range(nsite), neleca)
    link_indexb = cistring.gen_linkstr_index(range(nsite), nelecb)
    na = cistring.num_strings(nsite, neleca)
    nb = cistring.num_strings(nsite, nelecb)

    ci0 = fcivec.reshape(na,nb,-1)
    rdm1 = numpy.zeros((nsite,nsite))
    rdm2 = numpy.zeros((nsite,nsite,nsite,nsite))
    for str0 in range(na):
        t1 = numpy.zeros((nsite,nsite,nb)+ci0.shape[2:])
        for a, i, str1, sign in link_indexa[str0]:
            t1[i,a,:] += sign * ci0[str1,:]

        for k, tab in enumerate(link_indexb):
            for a, i, str1, sign in tab:
                t1[i,a,k] += sign * ci0[str0,str1]

        rdm1 += numpy.einsum('mp,ijmp->ij', ci0[str0], t1)
        # i^+ j|0> => <0|j^+ i, so swap i and j
        #:rdm2 += numpy.einsum('ijmp,klmp->jikl', t1, t1)
        tmp = lib.dot(t1.reshape(nsite**2,-1), t1.reshape(nsite**2,-1).T)
        rdm2 += tmp.reshape((nsite,)*4).transpose(1,0,2,3)
    rdm1, rdm2 = rdm.reorder_rdm(rdm1, rdm2, True)
    return rdm1, rdm2

开发者ID:chrinide，项目名称:pyscf，代码行数:30，代码来源:direct_ep.py

示例8: make_rdm12

def make_rdm12(fcivec, norb, nelec, link_index=None, reorder=True):
    #(dm1a, dm1b), (dm2aa, dm2ab, dm2bb) = \
    #        make_rdm12s(fcivec, norb, nelec, link_index, reorder)
    #return dm1a+dm1b, dm2aa+dm2ab+dm2ab.transpose(2,3,0,1)+dm2bb
    dm1, dm2 = rdm.make_rdm12_spin1('FCIrdm12kern_sf', fcivec, fcivec,
                                    norb, nelec, link_index, 1)
    if reorder:
        dm1, dm2 = rdm.reorder_rdm(dm1, dm2, inplace=True)
    return dm1, dm2

开发者ID:diradical，项目名称:pyscf，代码行数:9，代码来源:direct_spin1.py

示例9: trans_rdm12

def trans_rdm12(cibra, ciket, norb, nelec, link_index=None, reorder=True):
    #(dm1a, dm1b), (dm2aa, dm2ab, dm2ba, dm2bb) = \
    #        trans_rdm12s(cibra, ciket, norb, nelec, link_index, reorder)
    #return dm1a+dm1b, dm2aa+dm2ab+dm2ba+dm2bb
    dm1, dm2 = rdm.make_rdm12_spin1('FCItdm12kern_sf', cibra, ciket,
                                    norb, nelec, link_index, 2)
    if reorder:
        dm1, dm2 = rdm.reorder_rdm(dm1, dm2, inplace=True)
    return dm1, dm2

开发者ID:diradical，项目名称:pyscf，代码行数:9，代码来源:direct_spin1.py

示例10: make_rdm12

def make_rdm12(fcivec, norb, nelec, link_index=None, reorder=True):
    # dm1, dm2 = rdm.make_rdm12('FCIrdm12kern_spin0', fcivec, fcivec,
    #                          norb, nelec, link_index, 1)
    # NOT use FCIrdm12kern_spin0 because for small system, the kernel may call
    # direct diagonalization, which may not fulfil  fcivec = fcivet.T
    dm1, dm2 = rdm.make_rdm12("FCIrdm12kern_sf", fcivec, fcivec, norb, nelec, link_index, 1)
    if reorder:
        dm1, dm2 = rdm.reorder_rdm(dm1, dm2, True)
    return dm1, dm2

开发者ID:Bismarrck，项目名称:pyscf，代码行数:9，代码来源:direct_spin0.py

示例11: trans_rdm12

def trans_rdm12(cibra, ciket, norb, nelec, link_index=None, reorder=True):
    r'''Spin traced transition 1- and 2-particle transition density matrices.

    1pdm[p,q] = :math:`\langle q^\dagger p\rangle`;
    2pdm[p,q,r,s] = :math:`\langle p^\dagger r^\dagger s q\rangle`.
    '''
    #(dm1a, dm1b), (dm2aa, dm2ab, dm2ba, dm2bb) = \
    #        trans_rdm12s(cibra, ciket, norb, nelec, link_index, reorder)
    #return dm1a+dm1b, dm2aa+dm2ab+dm2ba+dm2bb
    dm1, dm2 = rdm.make_rdm12_spin1('FCItdm12kern_sf', cibra, ciket,
                                    norb, nelec, link_index, 2)
    if reorder:
        dm1, dm2 = rdm.reorder_rdm(dm1, dm2, inplace=True)
    return dm1, dm2

开发者ID:chrinide，项目名称:pyscf，代码行数:14，代码来源:direct_spin1.py

示例12: make_rdm12

def make_rdm12(fcivec, norb, nelec, link_index=None, reorder=True):
    r'''Spin traced 1- and 2-particle density matrices.

    1pdm[p,q] = :math:`\langle q_\alpha^\dagger p_\alpha \rangle +
                       \langle q_\beta^\dagger  p_\beta \rangle`;
    2pdm[p,q,r,s] = :math:`\langle p_\alpha^\dagger r_\alpha^\dagger s_\alpha q_\alpha\rangle +
                           \langle p_\beta^\dagger  r_\alpha^\dagger s_\alpha q_\beta\rangle +
                           \langle p_\alpha^\dagger r_\beta^\dagger  s_\beta  q_\alpha\rangle +
                           \langle p_\beta^\dagger  r_\beta^\dagger  s_\beta  q_\beta\rangle`.

    Energy should be computed as
    E = einsum('pq,qp', h1, 1pdm) + 1/2 * einsum('pqrs,pqrs', eri, 2pdm)
    where h1[p,q] = <p|h|q> and eri[p,q,r,s] = (pq|rs)
    '''
    #(dm1a, dm1b), (dm2aa, dm2ab, dm2bb) = \
    #        make_rdm12s(fcivec, norb, nelec, link_index, reorder)
    #return dm1a+dm1b, dm2aa+dm2ab+dm2ab.transpose(2,3,0,1)+dm2bb
    dm1, dm2 = rdm.make_rdm12_spin1('FCIrdm12kern_sf', fcivec, fcivec,
                                    norb, nelec, link_index, 1)
    if reorder:
        dm1, dm2 = rdm.reorder_rdm(dm1, dm2, inplace=True)
    return dm1, dm2

开发者ID:chrinide，项目名称:pyscf，代码行数:22，代码来源:direct_spin1.py

示例13: trans_rdm12

def trans_rdm12(cibra, ciket, norb, nelec, link_index=None, reorder=True):
    dm1, dm2 = rdm.make_rdm12('FCItdm12kern_sf', cibra, ciket,
                              norb, nelec, link_index, 2)
    if reorder:
        dm1, dm2 = rdm.reorder_rdm(dm1, dm2, True)
    return dm1, dm2

开发者ID:BB-Goldstein，项目名称:pyscf，代码行数:6，代码来源:direct_spin0.py

示例14: make_rdm2_abba

def make_rdm2_abba(fcivec, norb, nelec):
    dm2 = _make_rdm2_abba(fcivec, norb, nelec)
    dm1a = rdm.make_rdm1_spin1('FCImake_rdm1a', fcivec, fcivec, norb, nelec)
    dm1a, dm2 = rdm.reorder_rdm(dm1a, dm2, inplace=True)
    return dm2

开发者ID:BB-Goldstein，项目名称:pyscf，代码行数:5，代码来源:spin_op.py

示例15: make_rdm2_baab

def make_rdm2_baab(fcivec, norb, nelec):
    dm2 = _make_rdm2_baab(fcivec, norb, nelec)
    dm1b = rdm.make_rdm1_spin1('FCImake_rdm1b', fcivec, fcivec, norb, nelec)
    dm1b, dm2 = rdm.reorder_rdm(dm1b, dm2, inplace=True)
    return dm2

开发者ID:BB-Goldstein，项目名称:pyscf，代码行数:5，代码来源:spin_op.py

示例16: make_rdm2_baab

def make_rdm2_baab(fcivec, norb, nelec):
    assert(fcivec.flags.c_contiguous)
    dm2 = _make_rdm2_baab(fcivec, norb, nelec)
    dm1b = rdm.make_rdm1_spin1('FCImake_rdm1b', fcivec, fcivec, norb, nelec)
    dm1b, dm2 = rdm.reorder_rdm(dm1b, dm2, inplace=True)
    return dm2

开发者ID:matk86，项目名称:pyscf，代码行数:6，代码来源:spin_op.py

注：本文中的pyscf.fci.rdm.reorder_rdm函数示例由纯净天空整理自Github/MSDocs等源码及文档管理平台，相关代码片段筛选自各路编程大神贡献的开源项目，源码版权归原作者所有，传播和使用请参考对应项目的License；未经允许，请勿转载。

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Python rdm.reorder_rdm函数代码示例

示例1: spin_square

示例2: make_rdm12s

示例3: trans_rdm12s

示例4: make_rdm12s

示例5: trans_rdm12s

示例6: spin_square

示例7: make_rdm12e

示例8: make_rdm12

示例9: trans_rdm12

示例10: make_rdm12

示例11: trans_rdm12

示例12: make_rdm12

示例13: trans_rdm12

示例14: make_rdm2_abba

示例15: make_rdm2_baab

示例16: make_rdm2_baab

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