There are a lot of different possibilities here depending on how detailed (and pretty) you want to get, your licensing, what infrastructure you have in place, etc.
The simplest, lowest common denominator option from within SQL Developer would be to open the Reports menu (View | Reports), go to All Reports | Data Dictionary Reports | Database Administration | Top SQL and select one of the reports there. Probably Top SQL by Buffer Gets or Top SQL by CPU. Those will open a report that will show the top SQL by logical I/O or CPU that is currently in the plan cache.
与恶龙缠斗过久,自身亦成为恶龙;凝视深渊过久,深渊将回以凝视…